[FoRK] CO2 -> 43% by weight of an ABS-replacement bioplastic

Damien Morton dmorton at bitfurnace.com
Tue Aug 14 20:22:02 PDT 2012

Wonder what energy input is required per unit CO2 'sequestered'

I wonder at what rate the polyethylene carbonate or propylene
carbonate degrades, as in, how long can the CO2 be considered to be
'sequestered' for. Wikipedia tells me that polypropylene carbonate has
a glass temperature of 25-40C, which is pretty low. My guess is that
it degrades pretty quickly.

On Tue, Aug 14, 2012 at 2:30 AM, Stephen Williams <sdw at lig.net> wrote:
> Now we know what to do with our excess CO2!  The future is plastic!
> Nifty, if viable.
> http://www.designnews.com/author.asp?section_id=1392&doc_id=244239
> ABS Alternative Made of CO2, Palm Oil & Starch
> Ann R. Thryft, Senior Technical Editor, Materials & Assembly
> 8/10/2012   4 comments
> A team headed by Siemens researchers have developed a substitute material
> for ABS by making a polymer from starch, palm oil, and carbon dioxide. The
> new material, a mixture containing poly-hydroxybutyrate (PHB), has similar
> properties.
> The unnamed plastic is the result of a three-year project, funded by the
> German Research Ministry, for research into the use of CO2 as a possible
> feedstock for polymers. In addition to scientists at Siemens' corporate
> technology global research unit, project partners included researchers from
> BASF, well known as a leader in sustainable plastics and chemicals, as well
> as Munich Technical University, and the University of Hamburg.
> More than 70 percent of the new plastic is made of renewable polymers. The
> PHB, which is made from raw materials such as palm oil and starch, is
> brittle. So BASF's polypropylene carbonate (PPC) was added to soften it. PPC
> is transparent, biodegradable, and resistant to light, and can also be
> processed easily. By weight, it is 43 percent CO2, which came from power
> plant emissions using a separation process.
> More than 70 percent of an ABS substitute is made from starch, palm oil, and
> carbon dioxide. The research team used it to manufacture a vacuum cleaner
> cover to demonstrate its usefulness in consumer products.
> (Source: Siemens)
> Standard polystyrene-based ABS, or acrylonitrite-butadiene-styrene, is an
> engineering-grade plastic frequently used in consumer electronics products.
> In the last few years, concern about styrene's toxicity has led to a search
> for alternatives. Although the jury is still out on whether it has cancerous
> effects, styrene is regarded as a hazardous chemical, at least for eye
> contact, skin contact, and ingestion or inhalation. The Environmental
> Protection Agency has listed it as a suspected toxin and is investigating
> its potential as a carcinogen, as is the US National Toxicity Program of the
> Department of Health and Human Services.
> The Siemens-led research team found that the new material is a good
> alternative for ABS. To demonstrate its practicality,
> Bosch-Siemens-Hausgeräte (BSH) made a vacuum cleaner cover out of the
> material. As a next step, the Siemens scientists, along with BSH and BASF,
> want to investigate whether they can replace other types of plastic that BSH
> uses with composite materials based on CO2.
> Other efforts have been made to corral CO2 and make it useful, including as
> a renewable feedstock for polymers. Novomer has partnered with Penford to
> jointly develop and commercialize composites that combine starch and PPC
> polymer for use in packaging materials. Starch blended co-polymers are not
> new. Usually, they combine starches with petrochemical-derived polymers.
> Bioplastics based on starch have been used in packaging and other consumer
> goods for several years. But creating them from CO2 certainly is new.
> Novomer is also commercializing a catalyst system that turns waste CO2 into
> polymers for applications that include packaging, sacrificial materials, and
> coating resins. Using the catalyst to combine CO2 with ethylene oxide
> creates polyethylene carbonate (PEC), while combining CO2 with propylene
> oxide creates PPC. The resulting low molecular weight polymers can be used
> for coating resins and adhesives, while high molecular weight polymers
> include thermoplastics and sacrificial materials for electronics.
> sdw
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